Alsina came out of the car and starting firing a gun, striking Blaney at least once.
Blaney was taken to Ashtabula County Medical Center for treatment and police say he is expected to fully recover from non-life-threatening injuries.
Police, deputies, state troopers, and state investigators searched much of the day for Alsina.
The manhunt that spanned two states ended late Monday night in Millcreek near Erie, Pennsylvania.
Alsina is facing a number of charges including the attempted aggravated murder of a police officer.
He has been in trouble before with the law and was considered armed and dangerous. Anyone with any information about Monday's shooting should call the police department at (440) 998-2221 or (440) 992-7172.